Distortion — the series
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The distortion a linear model cannot have
A small-signal model's output is a scaled copy of its input by construction, so it has no second harmonic and asking it for one is not a hard question but a meaningless one. Measured on the curve itself, an exponential produces one per cent of harmonic distortion at 1.03 mV of drive — seven times sooner than the 7.30 mV at which its gain is one per cent wrong.
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The point the device is never at
A device's linearity is specified by one number, and that number is a place on no curve. The third-order intercept is where two straight lines would cross if both went on being straight, and neither does. For a differential pair the crossing sits π²/4 — 7.84 decibels — above the largest output the device can produce at any drive whatever, and the arithmetic that says so contains no tail current and no temperature.
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The product that is not the third
Every distortion result in this field is odd-order, and the two-tone machinery has computed the second-order product on every call since the day it was written and thrown it away. On a bare exponential it is the drive over twice the thermal voltage — 1.934 × 10⁻² of the fundamental at a millivolt, against 1.870 × 10⁻⁴ for the third-order product, a ratio of 4Vₜ/a and a hundred and three to one. A differential pair puts it at 6.2 × 10⁻¹⁶. And degeneration removes it as D⁻² where it removes the third order as D⁴/|3 − 2D|, so a stage linearised until its third-order product is negligible is a stage whose distortion is almost entirely the one nobody measured.